4.8 Article

Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel- and Ruthenium-Catalyzed Alkyne Hydrohydroxymethylation with Formaldehyde

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 50, Issue 25, Pages 5686-5689

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201101496

Keywords

hydrohydroxymethylation; nickel; paraformaldehyde; reductive coupling; ruthenium

Funding

  1. Robert A. Welch Foundation [F-0038]
  2. NSF-ICC [CHE-1021640]
  3. NSF-DFG [BR 1646/6-1]
  4. University of Texas at Austin
  5. Center for Green Chemistry and Catalysis
  6. Freiburg Institute for Advanced Studies (FRIAS)

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