4.8 Article

Efficient and Selective Gas-Phase Monomethylation versus N-H Bond Activation of Ammonia by Bare Zn(CH3)(+): Atomic Zinc as a Leaving Group in an S(N)2 Reaction

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 50, Issue 23, Pages 5387-5391

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201100096

Keywords

amines; ammonia; C-N bond formation; DFT calculations; gas-phase reactions

Funding

  1. Deutsche Forschungsgemeinschaft [EXC 314/1]
  2. Stiftung Stipendien Fonds des Verbandes der Chemischen Industrie

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