Journal
INORGANIC CHEMISTRY
Volume 46, Issue 5, Pages 1517-1519Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic061972w
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- NIGMS NIH HHS [GM-068621, R01 GM068621-05, GM-48722, R01 GM048722-14, R01 GM068621, R01 GM048722] Funding Source: Medline
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Oxidation of 5,10,15,20-tetramesitylporphyrinatoiron(III) perchlorate, (TMP)Fe-III(ClO4), with ferric perchlorate in acetonitrile gave a metastable species identified as (TMP)Fe-IV(ClO4)(2) that decayed within seconds to the known isomeric species (TMP center dot+)Fe-III(ClO4)(2). Irradiation of the metastable species with 355 nm laser light gave a highly reactive transient that reacts with simple organic reductants (alkenes and arylalkanes) 5 orders of magnitude faster than known Compound I analogues, (TMP center dot+)Fe-IV(O)(X-).
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