4.7 Article

New pincer-type diphosphinito (POCOP) complexes of NiII and NiIII

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 9, Pages 978-980

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b613812h

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This communication reports the synthesis and characterization of the new, pincer-type, square-planar, 16-electron compounds {2,6-(OPP2i)(2)C6H3}(NiBr)-Br-II, 1, and {((P2POCH2)-P-i)(2)CH} (NiBr)-Br-II, 2, and the square-pyramidal, 17-electron complex {((Pr2POCH2)-P-i)(2)CH}(NiBr2)-Br-III,3.

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