Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 9, Pages 2452-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja068819l
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- NIGMS NIH HHS [R01 GM 073932-01] Funding Source: Medline
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The asymmetric intramolecular hydroamination of allenes catalyzed by phosphinegold(I)-bis-p-nitrobenzoate complexes is described. This reaction is applicable to the enantioselective formation of vinyl pyrrolidines and piperidines in 70-99% ee.
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