Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 10, Pages 2740-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja068201b
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The reaction of Cu(CF3SO3)(2) and cytidine in aqueous solution leads to the first example of a polynuclear copper(II)-cytidine complex of formula [Cu(H2O)(6)][Cu-8(Hcyd)(8)(CF3SO3)(4)](CF3SO3)(6)center dot 12H(2)O (H(2)cyd = cytidine). It shows a fascinating calixarene-like structure made up of octanuclear [Cu-8(Hcyd)(8)(CF3SO3)(4)](4+) wheel-shaped moieties that show receptor properties through multiple H-bonding interactions toward [Cu(H2O)(6)](2+) cations occupying the centers of the wheel.
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