Journal
ORGANIC LETTERS
Volume 9, Issue 6, Pages 1085-1088Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0700963
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A perylene bisimide derivative bearing two phenyl substituents with chiral solubilizing alkyl chains at the imide N atoms has been synthesized, and its self-assembly properties in solution and condensed phase have been investigated. Temperature-dependent CD spectra revealed the coexistence of two different kinds of chiral aggregates, differing in size and handedness. The chiral side chains effect a higher order within the self-assemblies, resulting in an increased charge-carrier mobility in the columnar liquid crystalline mesophase.
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