Journal
ORGANIC LETTERS
Volume 9, Issue 6, Pages 985-988Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol063031t
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A study concerning the gold(I)-catalyzed rearrangement of diversely substituted allenyl carbinol esters into functionalized 1,3-butadien-2-olesters is described. The mild conditions employed allow the efficient, rapid, and stereoselective synthesis of a variety of such compounds via a new 1,3-shift of an ester moiety onto a gold-activated allene.
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