Journal
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
Volume 138, Issue 1, Pages 55-59Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.mseb.2007.01.015
Keywords
molybdenum trioxide; intercalation; layered material; amine
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Molybdenum oxide nanocomposites with layered structures were prepared directly from commercial bulk MoO3 using alkylamines as the guests. By using molybdenum oxide-amines as the starting materials, novel molybdenum oxide-dye composite was synthesized. On the basis of X-ray diffraction, scanning electron microscopy and infrared results, a possible arrangement of alkylamines guests in the interlayer space of molybdenum oxide has been proposed. Moreover, the interactions between the inorganic host and the organic guests have been discussed. A linear relationship is observed between the interlayer distance and the number of carbon atoms in n-alkyl chains. (c) 2007 Elsevier B.V. All rights reserved.
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