Journal
ORGANIC LETTERS
Volume 9, Issue 6, Pages 1117-1119Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070082x
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A chiral diamine was found to catalyze enantioselective addition of ketones to nitroolefins in aqueous/saline/organic media. The products were obtained with excellent diastereoselectivities (synlanti = 99:1) and enantioselectivities up to 99%. The reaction could be facilitated using a mild acid.
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