Journal
ORGANIC LETTERS
Volume 9, Issue 6, Pages 1065-1068Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol063112p
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The enantioselective Bronsted acid catalyzed addition of methyleneaminopyrrolidine to N-Boc imines has been achieved in the presence of chiral phosphoric acids derived from 3,3'-di(phenanthryl)-H8-BINOL. The corresponding aminohydrazones have been isolated in good yields with enantiomeric excesses up to 90%.
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