Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 6, Pages 2240-2242Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo062453d
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Axially chiral BINAM N-heterocyclic carbene (NHC)-Rh-(III) complexes were applied in the enantioselective hydrosilylation of 3-oxo-3-arylpropionic acid methyl or ethyl esters. The reduction products 3-hydroxy-3-arylpropionic acid methyl or ethyl esters could be obtained in good yields with good to excellent enantioselectivities under mild conditions.
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