Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 6, Pages 2216-2219Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061346g
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A new application of (PhO)(3)P-halogen-based reagents to the synthesis of vinyl halides and gem-dihalides is described. Vinyl halides were prepared in good to excellent yields from enolizable ketones, whereas aldehydes afforded the corresponding gem-dihalides. The halogenation proceeded smoothly under mild conditions.
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