Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 11, Pages 3076-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja070263u
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Funding
- NIGMS NIH HHS [R01 GM3540, R01 GM063540-05, R01 GM063540] Funding Source: Medline
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A direct O-2-coupled Pd(II)-catalyzed enantioselective dialkoxylation of 2-propenylphenols has been developed by utilizing chiral quinoline oxazoline ligands. A detrimental effect of added copper salts on enantioselectivity was observed which is attributed to the displacement of the chiral ligand off of Pd(II).
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