Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 49, Issue 15, Pages 2668-2679Publisher
WILEY-BLACKWELL
DOI: 10.1002/anie.200906340
Keywords
asymmetry; desulfonylation; diversity-oriented synthesis; organocatalysis; sulfones
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Funding
- Danish National Research Foundation
- OChem School
- Carlsberg Foundation
- Deutsche Forschungsgemeinschaft
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Asymmetric organocatalysis has become a powerful tool for the synthesis of optically active compounds. Whereas early research mainly focused on combining simple reagents as a proof-of-concept for asymmetric organocatalysis; recent investigations are directed towards extending the concept to more target- and diversity-oriented synthesis. As a result of the many transformation possibilities and their ability to generate both nucleophilic and electrophilic reaction partners, sulfones have become especially important substrates in the field of organocatalysis.
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