Journal
ORGANOMETALLICS
Volume 26, Issue 7, Pages 1811-1815Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om061154b
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- Engineering and Physical Sciences Research Council [GR/S81605/01] Funding Source: researchfish
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Discrete cationic mono(arene) complexes of thallium(I), [Tl(Cp2Fe)](+) and [Tl(C6Me6)](+), were synthesized as [H2N{B(C6F5)(3)}(2)](-) salts. The Tl center dot center dot center dot centroid distance of 2.723 angstrom to the arene in [Tl(C6Me6)](+) is the shortest described to date. This remarkably strong arene pi-bonding is confirmed by DFT calculations, which give a Tl-C6Me6 interaction energy of 163 kJ mol(-1).
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