4.8 Article

Threading-followed-by-swelling: A new protocol for rotaxane synthesis

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 12, Pages 3500-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja069362i

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We describe the use of the new threading-followed-by-swelling protocol to synthesize molecular rotaxanes by modifying our previously reported oxygen-deficient macrocycle/dibenzylammonium ion molecular recognition system and using a cis-1-[(Z)-alk-1'-enyl]-2-vinylcyclopropane motif as the swellable terminal group.

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