Journal
ORGANIC LETTERS
Volume 9, Issue 7, Pages 1327-1329Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070173u
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A highly convergent, enantioselective synthesis of (+)-Sch 642305 is presented, which features a Mukaiyama-Michael addition followed by allylation to establish the syn-anti relationship of the three contiguous stereocenters. The 10-membered macrolactone was formed through ring-closing metathesis.
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