Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 111, Issue 12, Pages 4484-4486Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0702649
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We used infrared-visible sum frequency spectroscopy (IR-VIS SFG) to study the interfacial composition and structure of aqueous potassium thiocyanate electrolyte solutions. The IR-VIS SFG spectra reveal an enrichment of the thiocyanate ions at the air-electrolyte interface. They also give access to the vibrational features of the interfacial water, which are affected by the presence of the ions. Polarization-dependent measurements have been used for a determination of the orientation of the pseudohalide anion. The combined data gives a picture of the interfacial architecture on a molecular scale.
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