4.8 Article

Rhodium-catalyzed intramolecular alkyne-carbodiimide Pauson-Khand-type reaction

Journal

ORGANIC LETTERS
Volume 9, Issue 7, Pages 1239-1241

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol063123i

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An efficient, Rh-catalyzed intramolecular Pauson-Khand-type carbonylation of alkyne-carbodiimides leading to 4,5-dihydro-1H-pyrrolo[2,3-b]pyrrolin-2-ones and 1H-pyrrolo[2,3-b]indol-2-ones is described.

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