Journal
ORGANIC LETTERS
Volume 9, Issue 7, Pages 1283-1286Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070048i
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Several ligands based on the rigid, V-shaped structure of Troger's base bearing 2,2'-bipyridine and 2-pyridylmethanimine moieties have been synthesized. These ligands undergo diastereoselective self-assembly to dinuclear double-stranded D-2d-symmetric helicates upon coordination to copper(I) and silver(I) ions as elucidated by NMR techniques and ESI mass spectrometric methods.
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