Journal
ORGANIC LETTERS
Volume 9, Issue 7, Pages 1203-1206Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0631399
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A new method for easy removal of ruthenium from metathesis reactions by using a polar isocyanide is reported. This protocol removed most ruthenium byproducts from a variety of synthetically useful metatheses. Moreover, the isocyanide-promoted carbene insertion results in rapid destruction of carbene reactivity, demonstrated in the commonly used first- and second-generation Grubbs' carbenes.
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