Preparation of highly dispersed PEM fuel cell catalysts using electroless deposition methods

A methodology for the electroless deposition (ED) Of PtCl62- using dimethylamine borane (DMAB) on a Rh-seeded carbon support has been developed for electrochemical and fuel cell applications. This procedure required seeding the carbon with a Rh-precursor catalyst via wet impregnation prior to the exposure of an aqueous ED bath containing PtCl62-, DMAB, and sodium citrate (complexing/stabilizing agent). Kinetic parameters that affect the extent and rate of PtCl62- deposition include concentrations Of PtCl62-, DMAB, and sodium citrate as well as pH and concentrations of Rh seed sites. A linear relationship between rate and extent of PtCl62- deposition and DMAB and Rh concentrations was found while the citrate concentration had little effect on rate and a modest effect on extent. Lastly, extent Of PtCl62- deposition showed a maximum with respect to pH. Characterization of the Rh-seeded, carbon support by transmission electron microscopy (TEM) shows that the Rh particle diameters remain constant at 33-43 angstrom as the Rh weight loading increases from 0.4% to 2.2% to 4.4%. Further, after deposition of similar loadings of Pt, TEM analysis shows Pt particle diameters decrease with increasing Rh loading, since equal amounts of Pt were deposited on greater numbers of Rh seed particles. This pattern suggests a shell-core geometry, where Pt is deposited more or less uniformly around a Rh core. (c) 2006 Elsevier B.V. All rights reserved.