Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 7, Pages 2558-2563Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0625655
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Enantioselective copper-catalyzed allylic alkylations were performed on allylic bromides with a protected hydroxyl or amine functional group using several Grignard reagents and Taniaphos L1 as a ligand. The terminal olefin moiety in the products was transformed into various functional groups without racemization, providing facile access to a variety of versatile bifunctional chiral building blocks.
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