3.8 Article

Reinvestigation of trilithium phosphide, Li3P

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INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S1600536807008422

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The crystal structure of Li3P has been reinvestigated and confirmed by single-crystal data. The structure is built of Li+ and P3- ions stacked in two kinds of layers perpendicular to the c axis. Atoms Li1, Li2 and P reside at positions of (6) over bar m2, 3m and (6) over bar m2 site symmetry, respectively. The only free parameter, z, for Li2 is found to be 0.5839 (4).

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