4.6 Article

Aerobic oxidation of thiols to disulfides catalyzed by a manganese(III) Schiff-base complex

Journal

CATALYSIS COMMUNICATIONS
Volume 8, Issue 4, Pages 697-700

Publisher

ELSEVIER
DOI: 10.1016/j.catcom.2006.08.036

Keywords

thiols; oxidation; catalyst; selective oxidation; Mn(III); Schiff-base complex; disulfides

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The oxidative coupling of aromatic thiols into the corresponding disulfides using a manganese(III) Schiff-base complex as catalyst under aerated and mild conditions is described. This system provides an efficient, convenient and practical method for the syntheses of symmetrical disulfides. (c) 2006 Elsevier B.V. All rights reserved.

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