4.8 Article

Extreme rate acceleration by axial thiolate coordination on the isomerization of endoperoxide catalyzed by iron porphyrin

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 47, Issue 34, Pages 6438-6440

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.200800137

Keywords

cytochrome P450; endoperoxides; enzyme models; heme; ligand effects

Funding

  1. Ministry of Education, Science, Sports, and Culture (Japan) [18390039, 19028054]

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