Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 77, Issue 4, Pages 620-624Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070363207040202
Keywords
-
Categories
Ask authors/readers for more resources
A theoretical analysis of the geometry of the isolated homoconjugated ion formed by interaction of the pyridine molecule with the pyridinium cation was performed. With no o-substituents and no external electric field applied, the hydrogen bond is strongly asymmetric and is characterized by a low barrier to proton transfer between the two chemically equivalent structures. According to the calculations, the most probable averaged distance between the nitrogen atoms forming the hydrogen bond in such homoconjugated cations is about 2.7 +/- 0.1 angstrom.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available