Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 6, Pages 861-864Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600553
Keywords
carbonyl compounds; catalysis; C-H activation; ferric chloride; iron; oxidation
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A small amount of iron(III) chloride (2 mol%) catalyzes benzylic oxidations with tert-butyl hydroperoxide (TBHP) as oxidant in pyridine. The corresponding carbonyl compounds are obtained in high yields.
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