Journal
ENZYME AND MICROBIAL TECHNOLOGY
Volume 40, Issue 5, Pages 1095-1099Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.enzmictec.2006.08.027
Keywords
Candida antarctica lipase B; cross-linking; ionic liquids; immobilisation; 1-butyl-3-methylimidazolium nitrate; alcohol resolution; amine resolution
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Candida antarctica lipase 13, adsorbed and cross-linked on a polypropylene carrier, maintained its activity when dispersed in ionic liquids, such as [BMIm][NO3], that denatured the free enzyme. The acylations (kinetic resolutions) of I -phenylethanol (E > 500) and I-phenylethylamine (E= 95), when carried out in [BMIm][NO3], were slow in comparison with molecular solvents but highly enantioselective. (c) 2006 Elsevier Inc. All rights reserved.
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