Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 13, Pages 3820-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja070037k
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- ICREA Funding Source: Custom
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The solid-state packing of a two-component mixture consisting of the alpha,alpha,alpha,alpha steroisomer of a calix[4]pyrrole resorcinarene hybrid and tetramethylammonium chloride is controlled by the relative stoichiometry of the mixture in solution. The use of a high molar excess of the ammonium salt induces, in the solid state, a self-assembly process of the calix[4]pyrrole into a supramolecular hexameric structure that corresponds to an octahedron.
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