Journal
POLYMER
Volume 48, Issue 8, Pages 2187-2198Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2007.02.045
Keywords
monolithic materials; polymer materials; polymer synthesis
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The synthetic particularities for the synthesis of polymer-based monolithic materials are summarized. In this context, monoliths prepared via thermal-, UV- or electron-beam triggered free radical polymerization, controlled TEMPO-mediated radical polymerization, polyaddition, polycondensation as well as living ring-opening metathesis polymerization (ROMP) will be covered. Particular attention is devoted to the aspects of controlling pore sizes, pore volumes and pore size distributions as well as functionalization of these supports. Finally, selected, recent applications in separation science, (bio-) catalysis and chip technology will be summarized. (c) 2007 Elsevier Ltd. All rights reserved.
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