Journal
TETRAHEDRON LETTERS
Volume 48, Issue 15, Pages 2691-2695Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.02.066
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Highly efficient epoxidation of olefins by molecular oxygen with catalytic amount of manganese meso-tetraphenylporphyrin (Mn(TPP)) at the ppm level were reported. The catalyst conferred high activity and selectivity for the olefins epoxidation under ambient temperature and atmospheric pressure. The turnover number (TON) of the catalyst could reach up to 700 million, which is comparable to enzyme catalysis. (c) 2007 Elsevier Ltd. All rights reserved.
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