Journal
TETRAHEDRON LETTERS
Volume 48, Issue 15, Pages 2765-2768Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.02.050
Keywords
alkylation; amines; nitro compounds; nitrites; poly-methyihydrosiloxane
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The potential utility of polymethylhydrosiloxane (PMHS) as a reducing agent for reductive N-alkylation of aromatic amines and nitro compounds using nitriles as an alkylating agent and Pd(OH)(2)/C as a catalyst is described. The application of this method for the synthesis of several heterocyclic compounds is also reported. (c) 2007 Elsevier Ltd. All rights reserved.
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