Journal
TETRAHEDRON LETTERS
Volume 48, Issue 15, Pages 2787-2789Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.02.046
Keywords
photochemistry; cyclobutanone; oxacarbene; C-nucleosides
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Photochemistry of cyclobutanones in the presence of HCN or malononitrile give photoadducts derived from oxacarbene insertion into C-H. These intermediates are useful for the preparation of C-nucleosides by structural elaboration of the CN groups. (c) 2007 Elsevier Ltd. All rights reserved.
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