Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 14, Pages 4142-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja070364s
Keywords
-
Categories
Ask authors/readers for more resources
The polymerization of 1,3-dienes has been well-studied using an array of metal-containing complexes. Although a variety of (pi-allyl) Ni(II) catalysts have been shown to be active for diene polymerization, details concerning the mechanism of chain growth are largely speculative and supported primarily by DFT calculations. The observation by low-temperature NMR spectroscopy of the key intermediates and the catalyst resting states in the chain growth are described here and provide a more complete and detailed mechanism of butadiene polymerization.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available