Journal
ORGANIC LETTERS
Volume 9, Issue 8, Pages 1569-1571Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0703938
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[GRAPHICS] Arylmagnesiation of unfunctionalized alkynes in the presence of catalytic amounts of chromium(II) chloride and pivalic acid proceeds with high stereoselectivity. The alkenylmagnesium intermediate reacts with various electrophiles to afford the corresponding tetrasubstituted olefins in good yields.
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