Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 8, Pages 2794-2802Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo062349w
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Funding
- NIGMS NIH HHS [R01 GM017880, R01 GM017880-35, GM-17880-35] Funding Source: Medline
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Five alkyne-containing hemoprotein models have been synthesized in a convergent manner. Sonogashira coupling was used to introduce the alkyne functional group on the proximal imidazole before or after being attached on the porphyrin. One model was immobilized onto a gold electrode surface via copper(I)-catalyzed azide-alkyne cycloaddition (Sharpless click chemistry).
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