Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 126, Issue 14, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2719194
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The authors report an ambient-pressure differential scanning calorimetric study of a calcium metaphosphate glass that has been isostatically compressed slightly above its glass transition temperature and was frozen-in under pressure. It is shown that the enthalpy overshoot of the calorimetric glass transition is enhanced by this treatment. This enhancement is associated with a decrease in the apparent fictive temperature T-fA that is determined using the enthalpy-matching approach. The origin of this correlation is discussed. (c) 2007 American Institute of Physics.
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