Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 187, Issue 2-3, Pages 293-298Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2006.10.025
Keywords
synchrotron radiation; circular dichroism; absorption spectroscopy; vacuum ultraviolet; locked nucleosides
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Absorption and synchrotron radiation circular dichroism (SRCD) spectra of nucleosides and locked nucleosides containing either the adenine and thymine nucleobase were measured in the ultraviolet and vacuum ultraviolet (down to 176 nm) regions. The CD spectra strongly depend on the chemical structure of the sugar and the introduction of a methylene bridge that locks it into a specific conformation. Spectra of compounds with different configurations at the sugar atoms shed light on what determines the sign and intensity of the CD bands. (C) 2006 Elsevier B.V. All rights reserved.
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