Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 308, Issue 2, Pages 332-336Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2006.12.076
Keywords
W/O/W miniemulsion; magnetic polymer microspheres; preparation; morphology; particle size; magnetic properties
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Magnetic poly(styrene-co-acrylic acid-co-acrylamide) microspheres were prepared by water-in-oil-in-water (W/O/W) miniemulsion polymerization of monomers in the presence of Fe3O4 nanoparticles. The copolymerizable monomers of acrylic acid and acrylamide were used not only to modify the surfaces of the microspheres with functional groups, but also to act as viscosity regulators to control the morphology and size of these microspheres. It was experimentally observed that the surfaces of these microspheres were functionalized with -NH2 groups produced by copolymerization, the morphologies (sphere, ringlike, and one-hole) of the microspheres were controlled by the concentration of copolymerizable monomers, and all samples prepared were superparamagnetic. The possible mechanism of formation of these magnetic microspheres is also discussed. (c) 2007 Elsevier Inc. All rights reserved.
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