Journal
TETRAHEDRON-ASYMMETRY
Volume 18, Issue 6, Pages 705-709Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2007.03.008
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L-Proline derived C-2-symmetric chiral tetraamide 5b was found to behave as an effective Lewis basic catalyst in the enantioselective hydrosilylation of ketimines, affording high isolated yields (up to 95%) and moderate to high enantioselectivities (up to 86% ee) for a broad range of ketimines. A clear synergistic effect of the two identical diamide units of 5b was observed for asymmetric induction. (c) 2007 Elsevier Ltd. All rights reserved.
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