Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 28, Issue 8, Pages 962-965Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200600884
Keywords
amphiphiles; crosslinking; irradiation; macroporous polymers; self-organization
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Microporous films consisting of two-dimensionally ordered void structures - so-called honeycomb films - were produced by evaporation of polymer solutions under high humidity. Two types of poly(vinyl cinnamate)s were used: A newly synthesized amphiphilic poly(vinyl cinnamate) and a mixture of a commercial poly(vinyl cinnamate) and an amphiphilic poly-ion complex. Photo-crosslinking of the honeycomb structure could be achieved by UV irradiation while completely retaining the film morphology. The crosslinked films showed excellent stability against organic solvents.
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