Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 15, Pages 4528-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja070686w
Keywords
-
Categories
Ask authors/readers for more resources
The reactions of cyclopentadiene with alpha-keto-beta,gamma-unsaturated phosphonates or with nitroalkenes proceed through an unsymmetrical bis-pericyclic transition state to give both Diels-Alder and hetero-Diels-Alder cycloadducts. The change in periselectivity of the Lewis acid catalyzed reactions can be qualitatively rationalized by the change in the potential energy surface (PES) landscapes, which ultimately affects the branching ratio of these bis-pericyclic reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available