Journal
SYNLETT
Volume -, Issue 7, Pages 1153-1157Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-977429
Keywords
fluorine; DNA; asymmetric catalysis; copper; halogenation
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Enantioselective electrophilic fluorination of beta-keto esters with Selectfluor (R) catalyzed by DNA and a nonchiral ligand-Cu(II) complex is presented. The chirality transfer from DNA to the substrate appears to be caused by the intercalation or groove binding of the substrate-ligand-Cu(II) complex to DNA.
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