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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 16, Pages 4906-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja070919j
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A novel palladium-catalyzed cyclization-oxidation sequence yielding bicyclo[3.1.0]hexanes was developed. A mechanism involving a Pd(II)/Pd(IV) cycle was proposed. An S(N)2 C-O bond formation from an alkyl-palladium(IV) intermediate was also suggested.
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