Journal
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
Volume 139, Issue 1, Pages 55-61Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.mseb.2007.01.034
Keywords
solution combustion synthesis; CeAlO3; cerium oxides; solid-solid interfaces
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Phase evolution of CeO2/gamma-Al2O3 system synthesized from single step solution combustion method is examined here. The nominal compositions of ceria and alumina in (CeO2)(x)/(Al2O3)(1-x) are varied from x = 0.0 to 0.66 to yield end compositions, gamma-Al2O3 to stoichiometric CeAlO3 phase. For the composition x = 0, the phase formed is gamma-Al2O3, and for x = 0.2, CeAlO3 is formed over gamma-Al2O3. As the cerium content increased beyond x = 0.2, CeO2/CeAlO3/gamma-Al2O3 oxides are formed. Heating CeAlO3/gamma-Al2O3 in air above 700 degrees C resulted in transformation to CeO2/gamma-Al2O3 and the subsequent reduction in H-2 gave back CeAlO3/gamma-Al2O3. TEM studies showed CeAlO3 crystallites growth on gamma-Al2O3 and the oxidized sample showed CeO2 formation over CeAlO3, which in turn interfaced with gamma-Al2O3 phase. XPS analysis of CeAlO3/gamma-Al2O3 phase showed the presence of Ce in +3 and +4 state indicating surface oxidized CeAlO3 phase. Epitaxial relation for growth of CeAlO3 over gamma-Al2O3 and CeO2 over CeAlO3 is demonstrated in the study, where adhesion of CeO2 over gamma-Al2O3 is via CeAlO3 phase at the interface. (c) 2007 Elsevier B.V. All rights reserved.
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