Journal
ORGANIC LETTERS
Volume 9, Issue 9, Pages 1749-1752Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070445t
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In the presence of ruthenium-based olefin metathesis catalysts and triphenylphosphine, alpha,beta-unsaturated aldehydes can be olefinated with diazoacetates. This ruthenium-catalyzed transformation has been employed in tandem with olefin cross-metathesis to convert terminal olefins into 1,3-dienoic esters in a single operation.
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