Journal
ORGANIC LETTERS
Volume 9, Issue 9, Pages 1717-1720Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070400s
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The application of a one-pot palladium-catalyzed cycloisomerization of enynes 1/Diels-Alder cycloaddition/allylboration sequence efficiently generates tricyclic structures with complete control of the four stereogenic centers. Ruthenium and platinum catalysts perform distinct transformations providing other isomeric boron-substituted cyclic compounds.
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