4.6 Article

Structure and electrochemical properties of nanocarbon-coated Li3V2(PO4)3 prepared by sol-gel method

Journal

ELECTROCHIMICA ACTA
Volume 52, Issue 16, Pages 5281-5285

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2007.02.052

Keywords

lithiuni-ion battery; lithium vanadium phosphates; Li3V2(PO4)(3); carbon-coated Li3V2(PO4)(3); sol-gel method

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A liquid-based sol-gel method was developed to synthesize nanocarbon-coated Li3V2(PO4)(3). The products were characterized by XRD, SEM and electrochemical measurements. The results of Rietveld refinement analysis indicate that single-phase Li3V2-(PO4)(3) with monoclinic structure can be obtained in our experimental process. The discharge capacity of carbon-coated Li3V2(PO4)(3) was 152.6 mAh/g at the 50th cycle under 1C rate, with 95.4% retention rate of initial capacity. A high discharge capacity of 184.1 mAh/g can be obtained under 0.12C rate, and a capacity of 140.0 mAh/g can still be held at 3C rate. The cyclic voltammetric measurements indicate that the electrode reaction reversibility is enhanced due to the carbon-coating. SEM images show that the reduced particle size and well-dispersed carbon-coating can be responsible for the good electrochemical performance obtained in our experiments. (c) 2007 Elsevier Ltd. All rights reserved.

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